Student Theses and Dissertations
Date of Award
1975
Document Type
Thesis
Degree Name
Doctor of Philosophy (PhD)
Thesis Advisor
Frank Field
Abstract
The effect of temperature on the kinetics and thermodynamics of gaseous ion-molecule reactions were investigated by pulsed, high pressure (0.4 - 3.0 torr) mass spectrometry in the temperature range 100 - 650OK. In the context of kinetic temperature effects, the reactions investigated may be divided into three classes: (i) Fast bimolecular transfer reactions which proceed with collision rates, e.g. N2H+ + X ---XH+ + N2 (X = CH4, NH3, CH3CHO).
License and Reuse Information
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Recommended Citation
Mautner, Michael, "The Temperature Dependence of Reactions of Gaseous Ions: Kinetics and Thermodynamics of Transfer and Association Reactions" (1975). Student Theses and Dissertations. 549.
https://digitalcommons.rockefeller.edu/student_theses_and_dissertations/549
Comments
A thesis presented to the faculty of The Rockefeller University in partial fulfillment of the requirements for the degree of Doctor of Philosophy